(Dimethylformamide)(2-methylpropenoato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]manganese(II) perchlorate dimethylformamide solvate
نویسندگان
چکیده
In the title complex, [Mn(C(4)H(5)O(2))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra-dentate tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine mol-ecule, a bidentate 2-methacrylate anion and a dimethyl-formamide mol-ecule. The methyl groups of the coordinated dimethyl-formamide mol-ecule and the perchlorate anions are disordered over two positions with occupancy factors of 0.640 (8) and 0.360 (8).
منابع مشابه
(Dimethylformamide-κO)(2-hydroxybenzoato-κ2 O 1,O 1′)[tris(1-methyl-1H-benzimidazol-2-ylmethyl-κN 3)amine-κN]manganese(II) perchlorate dimethylformamide monosolvate
In the title complex, [Mn(C(7)H(5)O(3))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is coordinated in a slightly distorted monocapped trigonal-prismatic geometry. The tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine (Mentb) ligand coordinates in a tetra-dentate mode and the coordination is completed by a bis-chelating salicylate ligand and a dimethyl-formamide ligand. The hy-d...
متن کاملAcrylato[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]cobalt(II) perchlorate–dimethylformamide–methanol (2/2/3)
In the title complex, [Co(C(3)H(3)O(2))(C(27)H(27)N(7))]ClO(4)·C(3)H(7)NO·1.5CH(4)O, the Co(II) ion is five-coordinated by four N atoms from a tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine (mentb) ligand and one O atom from an acrylate ligand in a distorted trigonal-bipyramidal geometry with approximate mol-ecular C(3) symmetry. The atoms of the acrylate ligand are disordered over two sites,...
متن کاملSalicylato[tris(N-methylbenzimidazol-2-ylmethyl)amine]zinc(II) perchlorate dimethylformamide sesquisolvate
In the title complex, [Zn(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Zn(II) atom is five-coordinated by four N atoms from a tris-(N-methyl-benzimidazol-2-ylmeth-yl)amine ligand and one O atom from a salicylate ligand in a distorted trigonal-bipyramidal geometry (τ parameter = 0.84), with approximate mol-ecular C(3) symmetry. One dimethyl-formamide mol-ecule lies on a general positi...
متن کامل(Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate
In the title complex, [Cu(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·2C(3)H(7)NO, the Cu(II) ion is five-coordinated by four N atoms from the tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine ligand and an O atom of the monodentate salicylate ligand. The N(4)O donor set defines a coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal. The crystal structure is stabilized ...
متن کاملAcrylato[tris(1-methylbenzimidazol-2-ylmethyl)amine]zinc(II) perchlorate–dimethylformamide–methanol (1/1/1.5) at 153 (2) K
In the title complex, [Zn(C(3)H(3)O(2))(C(27)H(27)N(7))](ClO(4))·C(3)H(7)NO·1.5CH(4)O, the Zn(II) ion is five-coordinated by four N atoms from a tris-(1-methyl-benzimidazol-2-ylmeth-yl)amine (Mentb) ligand and one O atom from an acrylate ligand in a distorted trigonal-bipyramidal geometry with approximate mol-ecular C(3) symmetry. The atoms of the acrylate ligand are disordered over two sites, ...
متن کامل